To set a minimum order amount for a certain country in the store, the following code snippet helps. In addition, you should add a textual note to inform potential buyers about the minimum order amount in advance.
add_action( 'woocommerce_check_cart_items', 'cw_min_num_products' ); function cw_min_num_products() { if( is_cart() || is_checkout() ) { global $woocommerce; $minimum = 20; $county = array('DE'); $cart_tot_order = WC()->cart->total; if( $cart_tot_order < $minimum && in_array( WC()->customer->get_shipping_country(), $county ) ) { wc_add_notice( sprintf( '<strong>A Minimum order of $%s is required before checking out.</strong>' . '<br />Current order: $%s.', $minimum, $cart_tot_order ), 'error' ); } } }