To set a minimum order amount for a certain country in the store, the following code snippet helps. In addition, you should add a textual note to inform potential buyers about the minimum order amount in advance.
add_action( 'woocommerce_check_cart_items', 'cw_min_num_products' );
function cw_min_num_products() {
if( is_cart() || is_checkout() ) {
global $woocommerce;
$minimum = 20;
$county = array('DE');
$cart_tot_order = WC()->cart->total;
if( $cart_tot_order < $minimum && in_array( WC()->customer->get_shipping_country(), $county ) ) {
wc_add_notice( sprintf( '<strong>A Minimum order of $%s is required before checking out.</strong>'
. '<br />Current order: $%s.',
$minimum,
$cart_tot_order ),
'error' );
}
}
}